Understanding the mechanism of Pd-catalyzed allylic substitution of the cyclic difluorinated carbonates
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چکیده
منابع مشابه
Understanding the mechanism of Pd-catalyzed allylic substitution of the cyclic difluorinated carbonates
We present a mechanistic investigation of Pd-catalyzed allylic substitution of cyclic gem-difluorinated carbonates 1 and 4, previously employed in the synthesis of 3',3'-difluoro-2'-hydroxymethyl-4',5'-unsaturated carbocyclic nucleosides in 17 steps. The substitution features a reversal of regioselectivity caused by fluorine.
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ژورنال
عنوان ژورنال: Beilstein Journal of Organic Chemistry
سال: 2008
ISSN: 1860-5397
DOI: 10.3762/bjoc.4.18